Control system for fluid catalytic cracking process

ABSTRACT

Coke deposition rate in the reactor of a fluid cat cracker is controlled by varying the severity and conversion level in the reactor, while maintaining maximum air rate to the regenerator. The temperature at the outlet of the regenerator, which is an indication of afterburning and amount of coke buildup, is used to control reactor temperature and catalyst-to-oil ratio in the reactor (by resetting the reactor temperature recorder control, which in turn controls the flow of hot regenerated catalyst from the regenerator to the reactor), thus controlling coke deposition to make it commensurate with air supply by controlling the severity and conversion level in the reactor. The temperature in the regenerator catalyst bed is held constant by varying the recycle feed rate to the reactor in response to variations in such temperature.

United States Patent [72] Inventor John 11. Smith Ponca City, Okla. [21] Appl. No. 1,002 [22] Filed Jan. 6, 1970 [45] Patented Dec. 21, 1971 [73] Assignee Continental Oil Company Ponca City, Okla. Continuation-impart of application Ser. No. 756,659, Aug. 30, 1968, now Patent No. 3,513,087, which is a continuation-in-part 0! application Ser. No. 702,047, Jan. 31, 1968, now abandoned. This application Jan. 6, 1970,Ser. No. 1,002

[54] CONTROL SYSTEM FOR FLUID CATALYTIC CRACKING PROCESS 4 Claims, 1 Drawing Fig.

[52] U.S.Cl 208/159, 23/288 S, 208/164 [51] Int.Cl ..Cl0g 13/18 [50] Field of Search 208/164, 159, DIG. 1; 23/288 [56] References Cited UNITED STATES PATENTS 2,409,751 10/1946 Gerhold et a1. 208/163 3,175,968 3/1965 Berger 208/164 Primary Examiner-Herbert Levine Attorneys-Joseph C. Kotarski, Henry H. Huth, Robert 8.

Coleman. Jr., Jerry B. Peterson. Jack N. Shears and Carroll Palmer ABSTRACT: Coke deposition rate in the reactor of a fluid cat cracker is controlled by varying the severity and conversion level in the reactor, while maintaining maximum air rate to the regenerator. The temperature at the outlet of the regenerator, which is an indication of afterburning and amount of coke buildup, is used to control reactor temperature and catalystto-oil ratio in the reactor (by resetting the reactor temperature recorder control, which in turn controls the flow of hot regenerated catalyst from the regenerator to the reactor), thus controlling coke deposition to make it commensurate with air supply by controlling the severity and conversion level in the reactor. The temperature in the regenerator catalyst bed is held constant by varying the recycle feed rate to the reactor in response to variations in such temperature.

VAPORS TO FRACTIONATOR l6 FLUE GA 0| 521 s 0: I

| l l 3 I l9 STEAMv REGENERATOR me u 1 -+r l' 2 l I lo I |3 i l RESET I l PRC 50 Free I l l 1 RECYCLE I T T; |L STEAM 5 ra a 4o FRC FRC FRESH FEED --fll j SLURRY RECYCLE 4 ill *iT.

CONTROL SYSTEM FOR FLUID CATALYTIC CRACKING PROCESS CROSS-REFERENCES TO RELATED APPLICATIONS This is continuation-impart of U.S. Ser. No. 756,659, filed Aug. 30, I968, now U.S. Pat. No. 3,513,087, which in turn was a continuation-in-part of U.S. Ser. No. 702,047, filed Jan. 31,1968, and now abandoned.

This invention is an improved control system for a conventionalfluid catalytic cracker. The-improvement consists of a method and apparatus for maximizing the coke burning rate in the regenerator by operating the air compressor at maximum capacity and controlling the coke deposition rate in the reactor by varying the reaction severity in response to variations in air supply from the compressor. More specifically, the improvement consists of method and apparatus for controlling the temperature in the regenerator catalyst bed by varying the recycle feed rate to the reactor.

BACKGROUND The background of this invention is explained in U.S. Ser. No. 756,659, filed Aug. 30, 1968, which application is hereby incorporated in its entirety into this application.

SUMMARY OF THE INVENTION This invention is a specific variation in the concept disclosed and claimed in U.S. Ser. No. 756,659 and is directed to a method of maintaining a constant temperature in the regenerator catalyst bed in fluid catalytic cracking units which do not have feed preheating furnaces. In U.S. Ser. No. 756,659 the unit included feed preheating furnace 6, and the temperature in the regenerator catalyst bed 10 was maintained constant by means of TRC 11 which automatically reset TRCA 8 to control the fuel to furnace 6. In this invention the unit does not contain a furnace 6 and the regenerator catalyst bed temperature is held constant by regulating or varying the recycle feed rate in response to variations in the regenerator catalyst bed temperature. In other respects the concept and method and apparatus for operating the unit is the same as that ofU.S. Ser. No. 756,659.

DESCRIPTION OF THE DRAWING The FIGURE is a simplified flow diagram of a fluid catalytic cracking unit embodying my invention.

DETAILED DESCRIPTION Referring to the drawing, compressor 1 runs at maximum speed on governor control, delivering all the air it can compress into regenerator 2 in which the pressure is held constant (preferably at about 10-30 p.s.i.g.) by a pressure recorder controller (PRC) 3a operating a back pressure valve in the flue gas exit line 3. Fresh feed and recycle gas oil streams 4 and 5 each on flow rate control (FRC) 4a and 5a, join and pass into the reactor feed riser 7. The temperature in the dense phase of the regenerator is held constant by a temperature recorder controller (TRC) 11 which resets the control point of FRC 5a, which in turn controls the recycle feed rate.

Steam and slurry recycle from the fractionator (not shown) may also be charged to the reactor feed riser at constant rates as indicated. Regenerated catalyst from the dense phase in regenerator 2 flows via a standpipe l2 and slide valve 13 into the lower end of the reactor feed riser 7 where it mixes thoroughly with the steam and fresh feed and recycle feed streams. By virtue of its higher temperature (about l,220 F.), the regenerated catalyst surrenders heat to the combined oil feed stream, bringing it to the desired temperature to effect vaporization and cracking of the latter. The resultant vapors and steam flow up through the reactor feed riser into reactor 14, entraining the catalyst therewith. The temperature within the reactor is controlled to maintain a reactor temperature preferably within the range of about 890-960 F., by a tem- LII perature recorder controller alarm (TRCA) 15 which regulates the position of the slide valve 13 in the regenerated catalyst standpipe 12.

The amount of afterburning which occurs in regenerator 2 is controlled by controlling its flue gas exit temperature with a temperature recorder controller (TRC) 16 which resets the control point on TRCA 15 which directly controls the reactor temperature.

Spent catalyst from reactor l4 gravitates through stripper 17 wherein it is countercurrently swept with steam fed to the base of the stripper via line 18 controlled by a flow recorder control (FRC) 19. This steam stripping removes adsorbed and entrapped oil vapors from the spent catalyst and returns them to the reactor from whence they ultimately flow to the fractionator.

Stripped spent catalyst gravitates from the base of stripper 17 into regenerator 2 via spent catalyst standpipe 20 and slide valve 21. The position of slide valve 21 is regulated by a level recorder controller 22 to maintain a constant head of catalyst above the base of stripper. The catalyst level may extend up into the reactor if desired.

Except for very short term deviations, the heat input to a catalytic cracker must equal the heat output; otherwise system temperatures might rise or fall to damaging levels. The sum total heat input via combustion within the regenerator 2 must equal the sum of the radiation losses, the sensible heat surrendered to the flue gas leaving the regenerator, and the sensible, latent, and reaction heats surrendered to the product vapors from the reactor 14.

If, at any time, the temperature of the dense phase 10 in the regenerator should tend to drop, it would signify that the rate of heat removal from the system temporarily exceeded the rate of heat input; the regenerator TRC 11 would react by decreasing the control setting of FRC 5a. This in turn would decrease the recycle feed rate (line 5) to riser 7, thereby reducing the rate of heat withdrawal from the system and thus bringing heat input and output back into balance and returning the regenerator temperature to its control point. It is readily apparent that by reacting in opposite fashion, the control system just described will limit the degree to which the regenerator temperature can climb above the control point.

A typical unit operates at or near the following conditions:

Net heat of combustion Heat loss to flue gas Heat to process Air required Heat to process Heat to recycle [2,300 B.t.u./No. coke 3,100 B.t.u.INo. coke 9,200 B.t.u./No. coke I40 s.c.f./No. coke 66 B.t.u.ls.c.f. air 100,000 B.t.u.lbbl.

From the above it can be seen that the recycle rate must be changed by 950 barrels a day to compensate for a change in air rate of 1,000 cubic foot per minute.

The control temperature setting on the TRC 16 must be somewhat higher than that on TRC 11 to insure controlled afterburning. This difference should be at least 5 F. to ensure reasonable controllability but should not be so high as to be wasteful of air that might be better used for burning additional coke which would result from raising conversion. In some instances it might be desirable to operate with a flue gas exit temperature 50 F. or more above the regenerator dense phase temperature to maintain a high mean oxygen concentration in the gases rising through the dense phase to reduce the residual coke content on regenerated catalyst to a lower level than would otherwise be achieved. For this control scheme to function properly, it is obviously necessary that the controlled temperature level in the regenerator dense phase exceed the ignition temperature of carbon monoxide. The preferred temperature is about l,200 to 1,225 F.

If, at any time, the temperature of the flue gas exiting from the top of regenerator should tend to fall below the control point, it would signify that there was a reduction in afterburning because of a drop in oxygen content of the flue gases rising from the dense phase. This in turn would signify that the means concentration of coke on catalyst in the regenerator was rising which would means that coke was being deposited at a faster rate than it was being burned. The flue gas TRC 16 would immediately lower the control setting on the TRCA which would, in turn, reposition (reduce the opening of) the slide valve 13 in the regenerated catalyst standpipe 12. The combination of lower reaction temperature and lower catalyst-to-oil ratio would reduce coke deposition rate by reducing conversion level until coke deposition rate again became commensurate with regeneration air rate (line In). It is readily apparent that if the flue gas exiting temperature should tend to rise, it would signify that coke was being deposited at a lesser rate than it was being burned and that the automatic control action would be the exact opposite of that just described to increase conversion rate until the coke deposition and burning rates again became equal. A change in reactor temperature of about 0.5 to 1.0" F. will compensate for a change of one percent in air rate or coke yield tendency of the feed stock.

in actual operation, the system may be simplified further by substituting potentiometers or other temperature sensing means for TRC l6 and allowing the operator to manually reset TRCA 15.

The reactor temperature control 15 includes highand lowtemperature alarms which alert the operator if the temperature reaches either alarm setting. The operator then takes appropriate action to bring the reactor temperature back within the prescribed range. For example, if the high-temperature alarm should sound, he would take some action to increase the severity of some reaction control variable other than temperature. This might be an increase in reactor catalyst level, catalyst activity, or slurry recycle rate, or a reduction in dilution steam rate to the riser or regenerator dense phase temperature. If the low temperature alarm should sound, the operator would take some action opposite to those just described. Alternatively, the reactor temperature control might be equipped with one or more reset mechanisms to automatically effect one or more of the changes indicated.

Although the control system could be made more complex as indicated in the last paragraph, I prefer the simple version as described and depicted in the drawing, relying upon the operator to take appropriate action to keep the reactor temperature within the alarm settings.

This plan of control will improve the results obtainable with any feedstock otherwise suitable for catalytic cracking and will be especially beneficial for any feedstock that varies in quality during operations.

Suitable catalysts are conventional fluid catalytic cracking catalysts, which are well known in the art.

What is considered new and inventive in this present invention is defined in the hereunto appended claims, it being understood, of course, that equivalents known to those skilled in the art are to be construed as within the scope and purview of the claims.

lclaim:

1. In the continuous process of cracking a hydrocarbon feedstock in the presence of subdivided catalyst particles, wherein the hydrocarbon stream effects a fluidized contacting of the particles in a reactor, conversion products are separated from the contacted particles, separated catalyst particles containing coke deposited hereon effect fluidized contacting of air in a separate regenerator, said air being supplied by an air compressor, combustion gas products are separated from regenerated catalyst particles and such regenerated catalyst particles with a reduced coke content are returned to the reactor for contact with hydrocarbon feedstock, the air compressor operated at maximum capacity with all of the air output going into the regenerator, the coke deposition rate in the reactor is controlled by varying the reaction severity in the reactor in response to variations in the air supply from the compressor, the reaction severity in the reactor is controlled by varying the temperature and the catalyst-to-feedstock ratio in the reactor in response to the temperature at the outlet of the regenerator while the temperature in the regenerator catalyst bed is held constant; the improvement which comprises holding said regenerator catalyst bed temperature constant by varying the recycle feed rate in response to variations in said regenerator catalyst bed temperature.

2. The process of claim 1 in which the temperature and the catalyst-to-feedstock ratio in the reactor are varied by varying the flow of hot regenerated catalyst from the regenerator to the reactor.

3. In a catalytic cracking unit consisting essentially of:

a, A reactor having a first conduit attached to the upper portion thereof, a stripper attached to lower portion thereof, and a temperature recorder controller alarm attached to said reactor;

b. a regenerator having attached to the upper portion thereof a second conduit and means to control the pressure in the regenerator, and having attached to the lower portion thereof a third conduit, equipped with a valve, said third conduit extending up into the lower portion of the regenerator, and a fourth conduit connected to the lower portion of the regenerator, said fourth conduit having an air compressor connected thereto;

c. means for controlling the operation of said valve in response to temperature variations in the reactor;

d. a fifth conduit connecting the lower portion of the reactor with the bottom end of said third conduit and extending beyond said connection to connect with a sixth conduit for fresh feed and a seventh conduit for recycle feed;

e. flow rate control means in each of said sixth and seventh conduits;

f. temperature-sensing means connected to the upper portion of the regenerator, said temperature-sensing means being operatively connected to said means (0);

The improvement which comprises:

g. Temperature-sensing means connected to the lower portion of the regenerator, said temperature-sensing means being operatively connected to said flow rate control means in said seventh conduit.

4. The combination of claim 3 wherein said temperature sensing means (g) comprises temperature control means for changing the control setting of said flow rate control means in response to temperature variations in the lower portion of the regenerator.

mg? I UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,629,097 Da December 21, 1971 Inventofls) John H. Smith It is certified that error appears in the above-identified patent and that said Letters Patent are-hereby corrected as shown below:

001. 1, after the first paragraph, should be the heading -I I -Disc1osure--.

Col. 2, line 20. after "controller" should be --(LRC)-. v

Col. 3, line 8, "means should be ---mean--. 001. 3, line 11, after "the" should be --reactor--. Col. 4, line '12,- efter "sor" should be ---is--.

*Symbol fox-pounds.

Signed and sealed this Lpth day of July 1972.

(SEAL) Attest:

EDWARD M.FLETCHER,JR. I ROBERT GOTTSCHALK Attesting Officer I Commissioner of Patents UNITED STATES PATENT OFFICE CERTIFICATE OF CORREUHUN Patent No, 3,629,097 Dated December 21, 197].

Inventor(s) John H. Smith It is certified that error appears in the above-identified patent and that said Letters Patentare hereby corrected as shown below:

Column 2, line 54, "No." should appear lbs.

line 55, "No." should appear lbsm --3 line 56, "No."

should appear lbs. line 57, "No." should appear Signed and sealed chi 812th d y of December 1972.

(SEAL) 'Attest:

Em: mmarcmmm; 4 ROBERT GOTTSCHALK Attesting Officer Commissioner of Patents USCOMM-DC 60376-5 69 Q U.$. GOVERNMENT PRINTING OFFICE: 1955 0-366-334.

5 FORM 1 0-1050 (10-69) 

2. The process of claim 1 in which the temperature and the catalyst-to-feedstock ratio in the reactor are varied by varying the flow of hot regenerated catalyst from the regenerator to the reactor.
 3. In a catalytic cracking unit consisting essentially of: a. A reactor having a first conduit attached to the upper portion thereof, a stripper attached to lower portion thereof, and a temperature recorder controller alarm attached to said reactor; b. a regenerator having attached to the upper portion thereof a second conduit and means to control the pressure in the regenerator, and having attached to the lower portion thereof a third conduit, equipped with a valve, said third conduit extending up into the lower portion of the regenerator, and a fourth conduit connected to the lower portion of the regenerator, said fourth conduit having an air compressor connected thereto; c. means for controlling the operation of said valve in response to temperature variations in the reactor; d. a fifth conduit connecting the lower portion of the reactor with the bottom end of said third conduit and extending beyond said connection to connect with a sixth conduit for fresh feed and a seventh conduit for recycle feed; e. flow rate control means in each of said sixth and seventh conduits; f. temperature-sensing means connected to the upper portion of the regenerAtor, said temperature-sensing means being operatively connected to said means (c); The improvement which comprises: g. Temperature-sensing means connected to the lower portion of the regenerator, said temperature-sensing means being operatively connected to said flow rate control means in said seventh conduit.
 4. The combination of claim 3 wherein said temperature sensing means (g) comprises temperature control means for changing the control setting of said flow rate control means in response to temperature variations in the lower portion of the regenerator. 